I always contribute BER to the plants inability to uptake certain nutrients. Usually caused by water logging, and leading to an unhealthy environment for the root system which causes root systems to die back, I find BER is more notorious in containers for the exact same reasons.
In the case with chuck, Epson salts add Magnesium sulfate, which has been shown to aid in the uptake of other nutrients. The magnesium might be low or be getting locked out for other reasons and applying a dosage of it could potentially make the magnesium, and other nutrients more readily available.